In continuation of our efforts to explore the synthetic utility of phosphomolybdic acid supported on silica gel pmasio 2, we herein report for the first time, a direct and efficient method for the alkylation of indoles with benzylic alcohols using 10 mol% of phosphomolybdic acid supported on silica gel, pmasio 2 as the novel catalytic system. Phosphomolybdic acid article about phosphomolybdic acid by. Phosphomolybdic acid hydrate x x x phosphomolybdic acid x x 23475 xxxx legend. Reduction with uric acid or ironii sulfate produces a brown coloured compound. Phosphomolybdic acid solution northwest missouri state. The phosphomolybdic acidpicrosirius red technique should be useful in experiments designed to investigate the effects of collagen distribution on the electrical and mechanical behavior of cardiac.
Molybdophosphoric acid sodium salt, phosphomolybdic acid sodium salt hydrate. Phosphomolybdic acidsupported silica gel as efficient and. Phosphomolybdic acid hydrate is a versatile precursor material and reagent for the synthesis of composites of graphene oxide, carbon nanotubes, and molybdeum compounds. Phosphomolybdic acid, hydrate is a yellowgreen compound, freely soluble in water and polar organic solvents such as ethanol. Phosphomolybdic acid pma hydrate is primarily used in spectrophotometric determination of phosphate ions. It participates in the synthesis of molybdenum disulfide mos2reduced graphene oxide. Phosphomolybdic acid is a yellowgreen compound, freely soluble in water and polar organic solvents such as ethanol. An investigation of the role of phosphotungstic and phosphomolybdic acids in mallorylike trichrome methods showed unexpectedly that, rather than acting as mordants to anionic dyes, these polyacids selectively blocked staining of all tissue components other than connective tissue fibres to aniline blue and other similar fibrereactive dyes. The phosphomolybdic acid picrosirius red technique should be useful in experiments designed to investigate the effects of collagen distribution on the electrical and mechanical behavior of cardiac. Identification product name 12molybdophosphoric acid. Molybdophosphoric acid hydrate phosphomolybdic acid hydrate, acs reagent, acros organics.
The ratio of p,oa to mooa in the yellow precipi tate and acid was according to debray as 1. It is an electroactive material with the potential to serve as a cationinsertion electrode in hybrid organicinorganic molecular batteries. Phosphomolybdic acid from atom scientific chemical. How to involve phosphomolybdic acid pma in picrosirius. Articles of phosphomolybdic acid are included as well. Phosphomolybdic acid is a component of massons trichrome stain. Fisher scientific 1 reagent lane fair lawn, nj 07410. Pma oxidizes the phenothiazine derivative to a cationic free radical, forming a coloured salt. Phosphomolybdic is used as a stain for developing thinlayer chromatography plates, staining.
Connective tissue components were found to contain. A preliminary extraction is necessary if certain reductants sulphite or ascorbic acid are present as. Product name phosphomolybdic acid hydrate ac206385000. Phosphotungstic acid pta, tungstophosphoric acid tpa, is a heteropoly acid with the chemical formula h 3 p w 12 o 40. Because phosphomolybdic acid can give intensely colored reac tion products with many substances that are transparent to uvvisible light, it is the most commonly employed detection. P368 page 1 revision no 001 1216 6th ave n kent wa 98032 phone. Buy phosphomolybdic acid cas 51429744, a reagent used for. In continuation of our efforts to explore the synthetic utility of phosphomolybdic acid supported on silica gel pmasio 2, we herein report for the first time, a direct and efficient method for the alkylation of. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone.
Chemicalbook provide chemical industry users with phosphomolybdic acid boiling point melting point,phosphomolybdic acid density msds formula use,if. We also manufacture phosphomolybdic acid hydrate in solid form. The folindenis reagent was prepared by mixing 100 g sodium tungstate, 20 g phosphomolybdic acid and 50 ml phosphoric acid with 750 ml water. It participates in the synthesis of molybdenum disulfide mos 2reduced graphene oxide rgo composites. Phosphomolybdic acid is a component of massons trichrome stain organic synthesis. Phosphomolybdic acid, phosphomolybdic acid suppliers, cas. Phosphomolybdic acid article about phosphomolybdic acid. Pdf optimization of tlc detection by phosphomolybdic acid. Safety data sheet phosphomolybdic acid section 1 chemical product and company identification msds name. Chemical product and company identification product name. Phosphomolybdic acid is one of the components of the goldners trichrome stain used for tissue staining. Identification product name 12molybdophosphoric acid hydrate. Phosphomolybdic acid material safety data sheet integra chemical company 24 hour emergency response. How to involve phosphomolybdic acid pma in picrosirius red.
An investigation of the role of phosphotungstic and phosphomolybdic acids in mallorylike trichrome methods showed unexpectedly that, rather than acting as mordants to anionic dyes, these. Phosphomolybdic acid cas no 51429744 material safety data sheet sds msds. Phosphomolybdic acid, crystal, reagent, acs is a yellow green compound also known as molybdophosphoric acid or pma. Molybdophosphoric acid hydrate phosphomolybdic acid hydrate, acs. X listed e indicates a substance that is the subject of a section 5e consent order under tsca. It participates in the synthesis of molybdenum disulfide mos2reduced graphene oxide rgo composites.
F indicates a substance that is the subject of a section 5f rule under tsca. It is used as a reagent in thin layer chromatography for staining phenolics. High sugar can necessitate largecorrections by forming reactive. Ac417890000, ac417890050, ac417890250, 41789, a237100 synonyms. Phosphomolybdic is used as a stain for developing thinlayer chromatography plates, staining phenolics, hydrocarbon waxes, alkaloids, and steroids.
Phosphomolybdic acid 51429744 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Material safety data sheet msds phosphoric acid, 85%. Phosphomolybdic acid, ammonium salt hydrate revision date 19jan2018 disclaimer the information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Hybrid membranes were prepared by loading silicotungstic acid sta and phosphomolybdic acid pma, into polyvinyl alcohol pva matrix. Chitosanphosphomolybdic acid membranes allowed to get peak power of 60 mw cm. Material safety data sheet phosphomolybdic acid msds section 1. The role of phosphotungstic and phosphomolybdic acids in. Fabrication and application of silicotungstic acidpolyvinyl alcohol. Phosphomolybdic acid is one of the components of the goldners trichrome stain. It one of several components that make up massons trichrome.
The effect of phosphomolybdic acid on the stainability of connective tissue by various dyes. Safety data sheet creation date 24nov2010 revision date 22mar2018 revision number 1 1. This chemical is considered hazardous by the 2012 osha hazard communication standard 29 cfr. Phosphotungstic acid is less sensitive to reduction than phosphomolybdic acid. Molybdatophosphoric acid hydrate msds material safety data sheet or sds, coa and coq, dossiers, brochures and. Show this safety data sheet to the doctor in attendance. First aid measures get medical attention immediately. Rowley biochemical 10 electronics avenue danvers, ma 01923 for information, call. Phosphomolybdic acid, crystal, reagent, acs 51429744. Remove from source of exposure and get medical attention for any breathing difficulty. Phosphomolybdic acid is a yellowgreen compound, freely soluble in water. Debray prepared the free phosphomolybdic acid by digesting the yellow precipi tate with aqua regia.
Jun 02, 2017 organic chemistry a yellowgreen compound used as a reagent in thinlayer chromatography. Phosphomolybdic acid, also known as dodeca molybdophosphoric acid or pma is a component of massons trichrome stain. Reduction of nitrates, oxalates and phenols in fermented solardried stored cowpea vigna unguiculata l. Phosphomolybdic acid hydrate revision date 24jan2018 general advice immediate medical attention is required.
A preliminary extraction is necessary if certain reductants sulphite or ascorbic acid are present as stabilizers, as they will reduce the reagent to phosphomolybdenum blue. Phosphomolybdic acid material safety data sheet cas no. It is a yellowgreen compound, freely soluble in water and polar organic solvents such. Conjugated unsaturated compounds reduce pma to molybdenum blue. Identification product name 12molybdophosphoric acid hydrate cat no. Identification of the substancemixture and of the companyundertaking. Safety data sheet northwest missouri state university. It has been shown to be a good catalyst for the skraup reaction for the synthesis of substituted quinolines. The staining mechanisms for collagen and cytoplasma, and an axamination of the dye diffusion rate model of differential staining. Pma is a component in the 3color histology stain called massons trichrome.
Firstaid measures general advice immediate medical attention is required. Regulatory information this safety datasheet complies with the requirements of regulation ec no. Chemtrec 8004249300 outside usa 7035273887 msds number. Cs powder, distilled water and acetic acid 2% wv were mixed to achieve protonation. Phosphomolybdic acid is also occasionally used in acid catalyzed reactions in organic synthesis. Phosphomolybdic acid, phosphomolybdic acid suppliers, cas no. Phosphomolybdic acid hydrate 51429744 100 phosphomolybdic acid 12026572 4. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number. Molybdatophosphoric acid hydrate cas 51429744 100532. Pdf optimization of tlc detection by phosphomolybdic.
Page 1 of 8 msds phosphoric acid, 85% material safety data sheet msds phosphoric acid, 85% 1. Phosphomolybdic acid solution cas 12026572 scbt santa. Free support files, msds sheets each product pdf format scytek. Please request a quote above to receive pricing information based on your specifications. Sigmaaldrich offers a number of phosphomolybdic acid hydrate products.
Medical definition of phosphomolybdic acid merriamwebster. Incompatible with powdered metals, organic materials. Msds, 12200, cacodylic acid, free acid, dimethylarsinic acid. Phosphomolybdic acid is a yellow, crystalline powder, highly soluble in water. Phosphomolybdic acid, also known as dodeca molybdophosphoric acid or pma, is a. Phosphomolybdic acid, also known as dodeca molybdophosphoric acid is a component of massons trichrome stain. Phosphomolybdic acid hydrate is a heteropolyacid hydrate. The information given is designed only as a guidance for safe handling, use, processing, storage. Reduction of nitrates, oxalates and phenols in fermented. Phosphomolybdic acid solution is a versatile staining reagent used in chromatography and other applications available in typical concentrations of 1020% in polar organic solvents such as ethanol. It participates in the synthesis of molybdenum disulfide mos 2 reduced graphene oxide rgo composites. Phosphomolybdic acid hydrate safety data sheet pdf.
78 437 86 1052 283 958 214 1072 45 267 1037 424 590 753 188 368 159 280 1614 303 358 1083 1065 1373 1214 916 1176 222